The FischerTropsch process is an important reaction in both coal liquefaction and gas to liquids technology for producing liquid hydrocarbons. In the usual implementation, carbon monoxide and hydrogen, the feedstocks for FT, are produced from coal, natural gas, or biomass in a process known as gasification.
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Coal liquefaction is the "coal to liquids" process that takes two steps (coal gasification and gas to liquids) to "upgrade" coal to synthetic liquid fuels, such as synthetic diesel and synthetic gasoline. Coal liquefaction has been a proven technology used for over 100 years and is undergoing a renaissance by a number of companies that believe ...
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In coal liquefaction process initial coal particle size can be considered as one of the important process parameters. In this work, particles of coal are prepared by pulverisation and separation ...
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History. In the past, coal was converted to make coal gas, which was piped to customers to burn for illumination, heating, and cooking. High prices of oil and natural gas led to increased interest in "BTU Conversion" technologies such as gasification, methanation and liquefaction. The Synthetic Fuels Corporation was a governmentfunded corporation established in 1980 to create a market ...
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Investigation of the nonintegrated twostage coal liquefaction (NTSL) process was initiated at the Wilsonville Advanced Coal Liquefaction R and D Facility during May 1981 when the HOil hydrotreating unit came successfully online. The primary objective of this investigation is the development of a commercially feasible method of efficient ...
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The development of diagnostic instrumentation for monitoring coal liquefaction process streams is discussed. A sapphire optical fiber was used as an attenuated total reflectance (ATR) element in conjunction with Fourier transform infrared (FTIR) spectrometry to probe harsh liquefaction process streams. ATR provides a short, reproducible ...
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A coal liquefaction pilot plant of the NEDOL process, supported by the New Energy and Industrial Technology Development Organization (NEDO), was in successful operation for a total of 269 days at Kashima, Japan. The liquefaction section consisted of three reactors, 1 m in diameter, connected in series, and processed 150 tons of coal per day.
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Coal liquefaction is the process of converting solid coal into liquid fuel. This process has been developed as a means to utilize coal resources that are otherwise difficult to access and transport. The resulting liquid fuel, called synthetic crude oil, can be refined into a variety of fuels, including diesel, gasoline, and aviation fuel.
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article{osti_, title = {Novel use of residue from direct coal liquefaction process}, author = {Yang, Jianli and Wang, Zhaixia and Liu, Zhenyu and Zhang, Yuzhen}, abstractNote = {Direct coal liquefaction residue (DCLR) is, commonly, designed to be used as a feed stock for gasification or combustion. Use of DCLR as a value added product is very important for improving overall economy of ...
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Plasmochemical hydrogenation of coal is a new process of direct production of acetylene and alkenes in the gaseous phase, in contrast to traditional processes of coal hydrogenation (liquefaction). Propanebutane mixture (50% C 3 H 8 +50% C 4 H 10), 200 t −1, is used as a hydrogenating agent instead of hydrogen, 2000 t −1.
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The byproduct from this hydrocracking process of coal liquefaction is defined as the precursor through the further processing to make super hard asphalt (SHA) as shown in Fig. 1. SHA is a dark colored solid at ambient temperature, which normally is about 30% of the total coal used as the feedstock ( Wu and Xie, 2010 ).
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An improved coal liquefaction process is provided which enables conversion of a coaloil slurry to a synthetic crude refinable to produce larger yields of gasoline and diesel oil. The process is characterized by a twostep operation applied to the slurry prior to catalytic desulfurization and hydrogenation in which the slurry undergoes partial ...
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What is coal liquefaction? Also called Coal to Liquid (CTL) technology, it is an alternative route to produce diesel and gasoline and makes economic sense only in a world of high crude oil prices. The process involves gasification of coal, which in turn will produce synthetic gas (a mix of CO+H2). The synthetic gas can be liquefied to its fuel ...
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the process to dissolve the coal and to transfer externally produced hydrogen to the coal molecules. Catalytic liquefaction resembles solvent extraction, except that hydrogen is added to the coal with the aid of a catalyst. Figure presents the flow diagram of a typical solvent extraction or catalytic liquefaction plant. These coal ...
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In principle, the process of coal liquefaction involves chemical compounds which also occur in other carbochemical or petrochemical processes. It is well known that a number of these substances may be carcinogenic, teratogenic or mutagenic. The concentration of benzo(a)pyrene in coal liquefaction products can be between 50 and 60 μg g −1.
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Pyrite addition to a coal liquefaction process (22, 26) is controlled (118) in inverse proportion to the calcium content of the feed coal to maximize the F. ( C.) liquid yield per unit weight of pyrite added (110). The pyrite addition is controlled in this manner so as to minimize the amount of pyrite used and ...
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Coal Liquefaction It is an alternative route to produce diesel and gasoline and makes economic sense only in a world of high crude oil prices,Also called Coal to Liquid (CTL) technology. The process involves gasification of coal, which in turn will produce synthetic gas (a mix of CO+H2).
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The Hcoal process is to be installed at a site in Kentucky and will have a 600 tons/day coal capacity, small compared to the coal gasification demonstration plants under study. The comparative lack of activity in coal liquefaction compared to gasification is the result of the factors described in Section VII,C .
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An integrated coal pretreatment, liquefaction and gasification process is provided in which particulate coal is contacted with a vapor phase hydrogen donor solvent to swell the coal particles. The swollen coal particles are subjected to coal liquefaction conditions at relatively low temperatures.
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Coal liquefaction is a process in which coal is converted into liquid fuels or petrochemicals. There are several processes used to accomplish this task, the two most common being the "indirect route" and the "direct route". [1]
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Liquefaction. Coal liquefaction is a process of converting coal into liquid fuels or petrochemicals. There are several processes to accomplish this task. The two most common are the indirect route and the direct route [58, 59].
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The article contains sections titled: 1. Introduction Commercial Development Historical Background 2. Indirect Coal Liquefaction Preparation of Synthesis Gas Co...
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This process is the only coal liquefaction scheme currently in use on a relatively large commercial scale; South Africa is currently using the Fischer−Tropsch process on a commercial scale in their complex. Thus, coal is converted to gaseous products at temperatures in excess of 800°C (1470°F), and at moderate pressures, to produce ...
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Coal Liquefaction is the process of converting coal to liquid fuels. What is Coal Liquefaction? The process of coal liquefaction creates synthetic liquid fuels from solid as substitutes for various petroleum products. There are two types of liquefaction direct and indirect .
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Through a onestage liquefaction method using a powdered iron catalyst and hydrogen donor solvent, the NEDOL process can attain a high liquefied oil yield from a wide range of coal ranks under a mild reaction condition. Through these technical characteristics, the NEDOL process has the following advantages in commercialization.
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misc{etde_609560, title = {Effect of catalyst addition on coliquefaction process of coal and biomass in supercritical water; Chorinkaisui wo mochiita sekitan biomass doji ekika process ni okeru shokubai tenka koka} author = {Yokura, H, Nonaka, H, Matsumura, Y, Tsutsumi, A, and Yoshida, K} abstractNote = {Mixture of coal and cellulose was liquefied in supercritical water (400degC, 25 MPa ...
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Coal resources have been used to produce liquid transportation fuels by several process routes collectively referred to as coal liquefaction or, more generally stated, as coal to liquids (CTL). Early records of coal conversion to liquid fuel date to 1913 and an extraction process developed by Friedrich Bergius in Germany [ 7 ].
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A process for the liquefaction of coal wherein raw feed coal is dissolved in recycle solvent with a slurry containing recycle coal minerals in the presence of added hydrogen at elevated temperature and pressure. The highest boiling distillable dissolved liquid fraction is obtained from a vacuum distillation zone and is entirely recycled to ...
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Gasification While the goal of combustion is to produce the maximum amount of heat possible by oxidizing all the combustible material, the goal of gasification is to convert most of the combustible solids into combustible gases such as carbon monoxide, hydrogen, and methane. Gasification reactions
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Petroleum gas production. For producing petroleum gas, the optimal advanced oil processing ratio is 20:5:17 (advanced oil processing : heavy oil cracking : light oil cracking), and 8:2:7 is close enough. Using coal liquefaction, the ratio is 60:39:55 (coal liquefaction : heavy oil cracking : light oil cracking), and 12:8:11 is close enough.
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When considering the development of coal liquefaction process using syngas, in addition to the above typical processes, hydrothermal liquefaction process is a technology worthy of reference. Hydrothermal liquefaction [110], [111], [112] is an effective and emerging technology that can convert both coals and biomass containing high moisture ...
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Coal liquefaction is a process of converting coal into liquid hydrocarbons: liquid fuels and petrochemicals. This process is often known as "Coal to X" or "Carbon to X", where X can be many different hydrocarbonbased products. However, the most common process chain is "Coal to Liquid Fuels" (CTL).
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A process for liquefying a particulate coal feed to produce useful petroleumlike liquid products which comprises contacting; in a series of two or more coal liquefaction zones, or stages, graded with respect to temperature, an admixture of a polar compound; or compounds, a hydrogen donor solvent and particulate coal, the total effluent being passed in each instance from a low temperature zone ...
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Even while you are still burning coal, liquefaction and then burning the lightoil derived solid fuel is a good idea. It will generate large amounts of petrol for use in other things, and you get a large fraction of the energy value from the coal. 10 coal becomes 10 heavy oil, 15 light oil, and 20 petrol gas.
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4. Coal Liquefaction Coal liquefaction is the conversion of coal into a synthetic oil in order to supplement natural sources of petroleum. It is an attractive technology because 1) It is well developed and thus could be implemented fairly rapidly and 2) There are relatively large quantities of coal reserves. 5.
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